I-Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) CAS:32993-05-8

I-Chlorocyclopentadienylbis (triphenylphosphine)ruthenium (II) iyisikhuthazi esiguquguqukayo esinezinhlobo eziningi zezicelo ekuhlanganisweni kwezinto eziphilayo. Enye yezindlela zayo eziyinhloko zokusebenzisa i-hydrogenation yamakhemikhali angagcwalisiwe, njenge-alkenes, i-alkynes, kanye namakhemikhali aromatic asebenzayo. Le nhlanganisela ibonisa umsebenzi ophezulu wokwenza izinto zibe zintsha kanye nokukhetha kulezi zinguquko, okwenza ibe ithuluzi eliwusizo ekukhiqizweni kwamakhemikhali amahle, izinto ezisetshenziswayo zemithi, kanye namakhemikhali ezolimo. Ngaphezu kwe-hydrogenation, le nhlanganisela isetshenziswa futhi ekuphenduleni kwe-isomerization, lapho ingasiza khona ukuhlelwa kabusha kwezibopho ezimbili kanye namanye amaqembu asebenzayo kuma-molecule ezinto eziphilayo. Amandla ayo okusebenzisa izinqubo ze-isomerization ngokusebenza kahle okukhulu kanye nokulawula kuyenza ibe usizo ekuhlanganisweni kwama-molecule ezinto eziphilayo eziyinkimbinkimbi kanye nemikhiqizo yemvelo. Ngaphezu kwalokho, i-Chlorocyclopentadienylbis (triphenylphosphine)ruthenium (II) ithola izinhlelo zokusebenza emkhakheni we-CC kanye ne-CX bond-forming reactions. Isetshenziswe ekuhlanganisweni kwamakhemikhali ahlukahlukene ezinto eziphilayo, kufaka phakathi imikhiqizo yemvelo eyinkimbinkimbi, imithi, nezinto ezisebenzayo. Umsebenzi wayo wokuvuselela ngaphansi kwezimo ezithambile kanye nokuhambisana kwayo nezinhlobo eziningi zamaqembu asebenzayo kwenza kube yi-catalyst ebalulekile ekwakhiweni kwezibopho ezintsha ze-carbon-carbon kanye ne-carbon-heteroatom. Ngaphezu kwalokho, le nhlanganisela ye-ruthenium ibonise ithemba ekuthuthukisweni kobuchwepheshe bamandla obuqhubekayo. Isetshenziswa ekuguqulweni kwe-catalytic kwamakhemikhali atholakala ku-biomass kanye nokuhlanganiswa kwamafutha avuselelekayo namakhemikhali. Amandla ayo okwenza kube lula ukuguqulwa okuphumelelayo nokukhethiwe kwe-feedstocks evuselelekayo kunegalelo ekuthuthukisweni kwezinqubo zamakhemikhali eziqhubekayo nezinobungani nemvelo. Ngamafuphi, i-Chlorocyclopentadienylbis (triphenylphosphine)ruthenium (II) iyi-catalyst eguquguqukayo enezicelo ku-hydrogenation, i-isomerization, ukusabela kwezibopho, kanye nobuchwepheshe bamandla obuqhubekayo. Ukuzinza kwayo, ukusabela kwayo, kanye nokukhetha kwayo kwenza kube ithuluzi elibalulekile ekuhlanganisweni kwezinto eziphilayo kanye nokuthuthukiswa kwezinqubo zamakhemikhali eziqhubekayo.