I-Chloroaminodiphenylethylpentafluorophenylksulfonyl)amido((p-cymene)ruthenium(II)) CAS:1026995-71-0

Le nhlanganisela isetshenziswa kabanzi njenge-catalyst ezinguqukweni eziningi zamakhemikhali, okuhlanganisa ukwakheka kwesibopho se-carbon-carbon, i-hydrogenation, kanye nokusabela kokuhlangana okuhlanganisiwe. Isakhiwo sayo esiyingqayizivele siyivumela ukuthi isebenze futhi isebenze ama-substrate ahlukahlukene e-organic, okuholela ekwakhekeni kwama-molecule ayinkimbinkimbi anokukhetha okuphezulu kanye nokusebenza kahle. Ngaphezu kwalokho, i-(Chloroaminodiphenylethylpentafluorophenylksulfonyl)amido((p-cymene)ruthenium(II) ibonise imiphumela ethembisayo ku-catalysis engalingani, lapho ingadala i-chirality kuma-molecule asabelayo, okwenza kube nokuhlanganiswa kwama-compound e-enantiopure. Le mpahla ibaluleke kakhulu embonini yezemithi, lapho ama-molecule e-enantiopure ebalulekile ekuthuthukisweni kwemithi. Ukuguquguquka kanye nokusabela kwe-compound kuyenza ibe ithuluzi elibalulekile kumakhemikhali okwenziwa. Ingasiza ekuguqulweni okunzima, njengokwakheka kwezibopho ze-carbon-heteroatom kanye nokusebenza kwama-substrate angasebenzi, yandise amathuba okwenziwa kwabacwaningi. Ekuphetheni, i-(Chloroaminodiphenylethylpentafluorophenylksulfonyl)amido((p-cymene)ruthenium(II) iyinhlanganisela eyinkimbinkimbi enezicelo ezibalulekile njenge-catalyst ekuhlanganisweni kwezinto eziphilayo. Amandla ayo okusebenzisa ama-substrate ahlukahlukene kanye nokukhuthaza i-chirality ayenza ibe ithuluzi elibalulekile ekukhiqizweni kwama-molecule ayinkimbinkimbi, kufaka phakathi ama-compound e-enantiopure ngezinjongo zemithi.