i-carbanide, i-chloropalladium(1+),(1Z,5Z)-cycloocta-1,5-diene CAS:63936-85-6

I-Palladium(II) Chloro complex [(C8H12)(Cl)Pd] yakhiwa ngokuxhumana phakathi kwama-molecule e-PdCl4 kanye ne-trans-(1R,5S)-cycloocta-1,5-diene ngokusebenzisa izibopho ze-dative. Umkhiqizo ophumayo uqukethe i-dienyl ligand eyodwa eboshwe kuzo zonke izikhungo ezine zensimbi ngokusebenzisa i-eta-coordination. Le nhlanganisela inokuqina okuphezulu kokushisa ngenxa yamandla aqinile aphakathi kwamangqamuzana ngaphakathi kwesakhiwo. Ukusetshenziswa kwayo kulele kakhulu ezinqubweni ze-catalytic ezihilela ukusabela kokuxhumanisa okuwelanayo. Isibonelo, lolu hlobo lwenza kube lula ukwakheka kwesibopho se-C-C ngesikhathi se-Suzuki Coupling Reaction ehilela ukuhlanganisa ama-athomu e-carbon ahlanganisiwe e-sp2 ndawonye kusetshenziswa ama-boronic acid njengama-nucleophiles. Isibopho esisha esiphumelayo esikhiqizwayo sithuthukisa izakhiwo zezinto ezisetshenziswa kumadivayisi kagesi ngaleyo ndlela siwenze asebenze kangcono. Ngaphezu kwalokho, lesi sikhombisi sithola ukusetshenziswa ku-Sonogashira coupling reaction lapho ama-athomu e-sp hybridized ahlanganiswa khona kusetshenziswa ama-alkynes agcinayo okuholela ekwakhekeni kwesibopho se-C-C ngaleyo ndlela kwakhiwe amaqembu amasha asebenzayo anezinhlelo zokusebenza ezingaba khona emikhakheni ehlukahlukene kufaka phakathi ukuhlanganiswa kwezidakamizwa kanye nesayensi yezinto ezibonakalayo.