i-bromotris (i-triphenylphosphine) i-rhodium (I) i-CAS: 14973-89-8

I-catalyst kaWilkinson isetshenziswa ezinhlobonhlobo zokuguqulwa kwamakhemikhali, okuhlanganisa i-hydrogenation, i-hydrosilylation, kanye ne-hydroformylation reactions. Iphinde isetshenziswe ekukhiqizweni kwamakhemikhali amahle, imithi, kanye nezinto ezithuthukisiwe. Ikhono le-catalyst lokwenza izinqubo ezikhethiwe nezisebenzayo ze-catalytic lenze kwaba ithuluzi elibalulekile ekuthuthukisweni kwezindlela ezintsha zokwenziwa kanye nokukhiqizwa kwemikhiqizo yamakhemikhali eyigugu.

Enye yezindlela ezibaluleke kakhulu zokusebenzisa i-catalyst kaWilkinson ekukhiqizweni kwama-aldehyde aqondile nge-hydroformylation reaction. I-catalyst ikhuthaza ukufakwa okukhethekile kwe-carbon monoxide ne-hydrogen ku-olefin, okuholela ekwakhekeni kwe-aldehyde. Lokhu kusabela kusetshenziswa kabanzi ekukhiqizweni kwama-plasticizer, ama-detergent, namanye amakhemikhali abalulekile ezimboni.

I-catalyst kaWilkinson isetshenziswa futhi ekuhlanganiseni imikhiqizo yemvelo eyinkimbinkimbi kanye nezidakamizwa ezisetshenziswayo. Izakhiwo zayo eziyingqayizivele kanye nokusabela kwayo kuyenza ibe ithuluzi eliwusizo ekukhuthazeni ukuguqulwa okuhlukahlukene kwamakhemikhali. Ngaphezu kwalokho, isetshenziswa ekukhiqizeni amakhemikhali akhethekile, njenge-chiral ligands, nezinto ezithuthukisiwe, njenge-conductive polymers.

Sekukonke, i-Bromotris (triphenylphosphine) rhodium (I) noma i-catalyst kaWilkinson iyinhlanganisela eguquguqukayo enezicelo ezibalulekile ekuhlanganisweni kwezinto eziphilayo, isayensi yezinto zokwakha, kanye nezinqubo zamakhemikhali ezimbonini. Ukusetshenziswa kwayo okungenzeka kudlulela ekuthuthukisweni kwamabhethri asebenza kahle kakhulu namaseli kaphethiloli, lapho ukuzinza nokusebenza kahle emazingeni okushisa aphezulu kubalulekile. Ukubaluleka kwenhlanganisela emkhakheni we-organic chemistry kanye nokuhlanganiswa kwamakhemikhali ezimbonini akunakuphikiswa.